She's got that pregnant glow, but it is Angelina Jolie's humanitarian efforts that make her most radiant, according to People magazine.

In this image made available by People Magazine, who supplied this photo, has put Angelina Jolie --seen in a photo by James White -- on the cover of their '100 Most Beautiful' special double issue which is on newstands Friday, April 28, 2006. [AP]

The pillow-lipped actress graces the cover of People's "100 Most Beautiful People" issue, on newsstands Friday. It's her fourth time on the list, but first as cover girl.

"She looks the most beautiful when she's in the field ¡ª natural, no makeup, nothing," the magazine quotes musician Wyclef Jean, who worked with Jolie on a relief effort in Haiti. "Because you see Angelina, the angel. It doesn't get any better than that."

The magazine didn't forget her boyfriend Brad Pitt, or her two children, either. People named the globe-trotting Jolie-Pitt clan the "World's Most Beautiful Family."

The world may have to wait several more weeks for the arrival of the Brangelina offspring: Jolie told NBC News that she is shy of eight months pregnant, according to MSNBC's web site.

In the interview, which was set to air on Thursday's "Today" and on "Dateline" Sunday, Jolie also said she knows the baby's gender but did not disclose it, according to MSNBC. The actress, interviewed in Namibia, is awaiting the birth at an African resort.

Also making the "Beautiful People" list, which until this year was limited to 50: Halle Berry, Julia Roberts, George Clooney, Scarlett Johansson, Kirstie Alley, Ryan Seacrest and University of Southern California quarterback Matt Leinart.